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The Big One – (Explosive) – Complete all Mission Stories & Complete Five Assassination Challenges.The Iconator – (Explosive) – Complete all Mission Stories & Complete Four Assassination Challenges.Proximity Explosive Duck – (Explosive) – Complete Mission Story Challenges in Sapienza.Antique Emetic Syringe – (Poison) – Unlocked at Level 20.Jaeger 7 Lancer (Sniper Rifle) (Marksman, 2X Scope) – Unlocked at Level 20.
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Remote Breaching Charge (Explosive) – Unlocked at Level 15.Enram HV – (Shotgun) – Unlocked at Level 12.ICA Remote Audio Distraction – (Distraction) – Unlocked at Level 10.Combat Knife – (Melee) – Unlocked at Level 7.TAC-4 AR Auto – (Assault Rifle) – Unlocked at Level 5.Modern Lethal Syringe – (Poison) – Unlocked at Level 2.There are three mission stories shown after completing The mission Showstopper, these are the 3 required to unlock this challenge, not just any random 3 Sapienza (Legacy Pack) A New Bat – (Melee) – Complete all levels in the Corky Commotion Escalation Contract.ICA19 Silverballer – (Suppressed, Steady Aim) – Complete Mission Story Challenges in Paris**.ICA Remote Explosive – (Explosive) – Unlocks at Level 20.HWK 21 Covert – (Pistol) (Large Capacity, Suppressed) – Unlocked at Level 20.Lethal Poison Vial (Poison) – Unlocked at Level 15.Napoleon Blownaparte – (Explosive) – Unlocked at Level 10.Jaeger 7 (Sniper Rifle) (Lightweight) – Unlocked at Level 5.Sedative Poison Vial – (Poison) – Unlocked at Level 2.This will require escalations from multiple locations as the prologue by itself does not have 5. *5 “complete” escalations, not just 5/5 levels within one. ICA Tripwire Mine – (Explosive) – Complete final stage of any escalation with Silent Assassin rating.TAC-SMG – (SMG) (Suppressed, Steady-Aim) – Complete Five Escalations*.Lockpick – Complete Mission Story Challenges in ICA Facility.Hitman 2 Mastery and Challenge Unlocks Prologue (Legacy Pack) Important or interesting items are in bold. Also my recommendations for which items to focus on first that will give you more versatility quickly.
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This is a basic list of what item unlocks are available from which locations in the game.